Trace metal testing in complex matrices

We can accurately measure trace metals in complex matrices using our high resolution inductively coupled plasma mass spectrometry facilities.

Trace metals in aquatic environments

The level of trace metals in aquatic environments must be reliably and regularly monitored. This is done to protect fresh and marine waters.

The Australian and New Zealand Guidelines for Fresh and Marine Water Quality has proposed trigger values for a range of trace metals and metalloids. 

Our testing services

We can accurately measure trace metals in complex matrices.

We have high resolution inductively coupled plasma mass spectrometry (HR ICP-MS) facilities that can offer the following:

  • A signal-to-noise ratio 10 to 1000 times greater than ICP-MS C/R. ICP-MS C/R sensitivity will be enhanced or suppressed depending upon the cell conditions This sensitivity may need to be compromised when multiple elements are determined.
  • Resolution up to 0.001 mass units. This is up to 500 times greater than ICP-MS C/R. IT also allows separation of most common interferences.
  • Visual evidence (spectra) of the presence of interferences and allows characterisation of interference and analyte signal for each individual sample
  • Consistently reliable analysis of trace elements in complex matrices. This is due to its sensitivity and unique capability to resolve interferences from trace elements in complex sample types.

Most laboratories use quadrupole ICP-MS that frequently gives false positive results much higher than the true concentrations in the sample. 

Our reporting limits

These are our limits of reporting for each trace metal.

Element

Standard limit of reporting

(µg/L)

Low limit of reporting

(fresh water only) (µg/L)

Instrument
Ag 1 0.1 ICP-MS
Al 5 1 ICP-MS/ICP-AES
As 1 0.2 HR ICP-MS
Au 1 0.1 ICP-MS
B 5 1 ICP-MS/ICP-AES
Ba 1 0.1 ICP-MS/ICP-AES
Be 1 0.1 ICP-MS
Bi 1 0.1 ICP-MS
Br 5 5 ICP-MS
Ca 5 1 ICP-AES
Cd 0.1 0.05 ICP-MS
Ce 1 0.1 ICP-MS
Co 1 0.1 HR ICP-MS
Cr 1 0.2 HR ICP-MS
Cr III 5 1 not applicable
Cr VI 5 1 discrete analyser
Cs 1 0.1 ICP-MS
Cu 1 0.1 HR ICP-MS
Dy 1 0.1 ICP-MS
Er 1 0.1 ICP-MS
Eu 1 0.1 ICP-MS
Fe 5 5 ICP-AES
Ga 1 0.1 ICP-MS
Gd 1 0.1 ICP-MS
Ge 1 0.1 ICP-MS
Hf 1 0.1 ICP-MS
Hg 0.1 0.05 ICP-MS/CVAAS
Ho 1 0.1 ICP-MS
I 5 5 ICP-MS
In 1 0.1 ICP-MS
Ir 1 0.1 ICP-MS
K 50 20 ICP-AES
La 1 0.1 ICP-MS
Li 1 0.1 ICP-MS
Lu 1 0.1 ICP-MS
Mg 5 1 ICP-AES
Mn 1 0.1 ICP-MS
Mo 1 0.1 ICP-MS
Na 50 20 ICP-AES
Nb 1 0.1 ICP-MS
Nd 1 0.1 ICP-MS
Ni 1 0.1 HR ICP-MS
Os 1 0.1 ICP-MS
P 50 ICP-AES
P (low) 2 HR ICP-MS
Pb 1 0.1 ICP-MS
Pd 1 0.1 ICP-MS
Pr 1 0.1 ICP-MS
Pt 1 0.1 ICP-MS
Re 1 0.1 ICP-MS
Rb 1 0.1 ICP-MS
Rh 1 0.1 ICP-MS
Ru 1 0.1 ICP-MS
S 50 50 ICP-AES
Sb 1 0.1 ICP-MS
Sc 1 0.2 ICP-MS
Se 1 0.2 HR ICP-MS
Si 50 50 ICP-AES
Sm 1 0.1 ICP-MS
Sn 1 0.1 ICP-MS
Sr 1 0.1 ICP-MS
Ta 1 0.1 ICP-MS
Tb 1 0.1 ICP-MS
Te 1 0.1 ICP-MS
Th 1 0.1 ICP-MS
Tl 1 0.1 ICP-MS
Ti 1 1 ICP-MS/ICP-AES
Tm 1 0.1 ICP-MS
U 1 0.1 ICP-MS
V 1 0.2 HR ICP-MS
W 1 0.1 ICP-MS
Y 1 0.1 ICP-MS
Yb 1 0.1 ICP-MS
Zn 1 0.1 HR ICP-MS
Zr 1 0.1 ICP-MS

Limits of reporting against trigger values

These are our limits of reporting against the Australian and New Zealand Environment Conservation Council (ANZECC) trigger values for fresh and marine water.

Element Standard limit of reporting (µg/L) Low limit of reporting (fresh water only) (µg/L) ANZECC trigger values for fresh water (µg/L) Level of protection (99% species) ANZECC trigger values for fresh water (µg/L) Level of protection (95% species) ANZECC trigger values for marine water (µg/L) Level of protection  (99% species) ANZECC trigger values for marine water (µg/L) Level of protection  (95% species)
Ag 1 0.1 0.02 0.05 0.8 1.4
Al 5 1 27 55
B 5 1 90 370
Cd 0.1 0.05 0.06 0.2 0.7 5.5
Co 1 0.1 0.005 1
Cr III 5 1 7.7 27.4
Cr VI 5 1 0.01 1 0.14 4.4
Cu 1 0.1 1 1.1 0.3 1.3
Hg 0.1 0.05 0.06 0.6 0.1 0.4
Mn 1 0.1 1200 1900
Ni 1 0.1 8 11 7 70
Pb 1 0.1 1 3.4 2.2 4.4
Se 1 0.2 5 11
V 1 0.2 50 100
Zn 1 0.1 2.4 8 7 15

Trace metals in aquatic environments

The level of trace metals in aquatic environments must be reliably and regularly monitored. This is done to protect fresh and marine waters.

The Australian and New Zealand Guidelines for Fresh and Marine Water Quality has proposed trigger values for a range of trace metals and metalloids. 

Our testing services

We can accurately measure trace metals in complex matrices.

We have high resolution inductively coupled plasma mass spectrometry (HR ICP-MS) facilities that can offer the following:

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